ic060056f_si_001.cif (25.39 kB)
One-Dimensional μ-Chloromanganese(II)−Tetrathiafulvalene (TTF) Coordination Compound
dataset
posted on 2006-04-17, 00:00 authored by Chunyang Jia, Shi-Xia Liu, Christina Ambrus, Antonia Neels, Gaël Labat, Silvio DecurtinsA new tetrathiafulvalene derivative 1 bearing a single pyridine group
and its coordination complex 2, with stoichiometry [Mn(μ-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The
complex 2 shows an extended chain structure, which is potentially
favorable for electrical conductivity. Notably, this is the first
monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.
