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One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst

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Version 2 2019-12-02, 19:33
Version 1 2019-11-19, 08:29
journal contribution
posted on 2019-12-02, 19:33 authored by Jingcheng Wu, Xinghua Zhang, Qiang Chen, Lungang Chen, Qiying Liu, Chenguang Wang, Longlong Ma
Furfural (FAL), a promising renewable platform compound from biomass, can be totally hydrogenated to an industrially important platform chemical, tetrahydrofurfuryl alcohol (THFA). In this work, a high yield of THFA was obtained by one-pot hydrogenation of FAL over a PtNi catalyst under mild reaction conditions. Small PtNi alloy particles were well distributed on active carbon. The catalysts were characterized by several physical–chemical technologies (transmission electron microscopy, X-ray diffraction, energy-dispersive spectroscopy, and inductively coupled plasma spectroscopy). Temperature-programmed reduction with hydrogen and in situ X-ray photoelectron spectroscopy demonstrate the presence of PtNi alloy. The electron-rich metal Pt could facilitate the heterolytic dissociation of hydrogen and promote the hydrogenation of FAL. Pt sites on the surface facilitate the adsorption at aldehyde (CO) groups, and the furan ring strongly adsorbs on the Ni surface. Low reaction temperature is advantageous to reduce side reactions. Various metal concentrations were employed in this reaction; Pt(3)­Ni(3)/C catalyst exhibits the best performance, achieving 99% FAL conversion and 93% THFA yield at 35 °C and under 2 MPa H2.

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