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Novel Multifunctional Zn Metal–Organic Framework Fluorescent Probe Demonstrating Unique Sensitivity and Selectivity for Detection of PA and Fe3+ Ions in Water Solution
journal contribution
posted on 2019-08-28, 15:09 authored by Xinrui Zhuang, Xiao Zhang, Nanxi Zhang, Yan Wang, Liyan Zhao, Qingfeng YangA novel metal–organic
framework {Zn2(tpt)2(tad)2·H2O} (tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine,
H2tda = 2,5-thiophene dicarboxylic acid) with a 3-fold
interpenetrating 3D framework was successfully synthesized under hydrothermal
conditions. As expected, 1 displays excellent luminescence
and can stably exist in different pure organic solvents and acid–base
solution. 1 can be considered as an ultrasensitive sensor
for detection of Fe3+ ions and PA with high selectivity
by fluorescence quenching behaviors. Meanwhile, the fluorescence test
plates show the visible color change of Fe3+ ions which
can be easily observed by the naked eye in the detection process,
which makes Fe3+ ions more easily recognized than various
metal ions. In addition, the mechanism of fluorescence quenching is
also further discussed.