ie6b00664_si_001.pdf (193.12 kB)
Novel Inverse Supported Ionic Liquid Absorbents for Acidic Gas Removal from Flue Gas
journal contribution
posted on 2016-04-18, 00:00 authored by D. S. Karousos, E. Kouvelos, A. Sapalidis, K. Pohako-Esko, M. Bahlmann, P. S. Schulz, P. Wasserscheid, E. Siranidi, O. Vangeli, P. Falaras, N. Kanellopoulos, G. Em. RomanosThis
work reports on the astonishing high capacity of inverse supported
ionic liquid absorbents, hereinafter denoted as “inverse SILPs”
to remove acidic gases (SO2 and CO2) from flue
gas streams. These nonconventional SILPs are easily prepared in the
form of flowing powder via a phase inversion technique and consist
of tiny ionic liquid (IL) droplets enclosed into an ultrathin, porous
solid sleeve of pyrogenic silica nanoparticles. The CO2/N2 and SO2/CO2 separation performance
and regeneration efficiency of inverse SILPs developed from six different
ILs and two IL/chitosan ionogels was examined via gravimetric CO2, N2 absorption isotherms and via SO2, CO2, O2 breakthrough curves from gas mixtures
in fixed beds. The involved ILs varied from chemisorbing ones, composed
of alkyl- or alkanol-ammonium cations and amino acid anions, to physisorbing
ones including ether functionalized anions and 1-alkyl-3-methylimidazolium
cations. It is noteworthy that the best performing inverse SILP consisted
of a very common IL, the 1-butyl-3-methylimidazolium chloride [BMIM][Cl],
the absorption capacity of which was slightly enhanced by dissolving
5 wt % of chitosan to form the respective ionogel. The material’s
performance was stable in repeated cycles of absorption and regeneration
at 60 °C under helium flow, exhibiting SO2/CO2 selectivity of above 300, while the SO2 and CO2 absorption capacity was 1.6 and 0.6 mmol/g respectively at
25 °C, in a gas stream of 1 bar composed of 0.13 vol % SO2, 13 vol % CO2, 11.5 vol % O2 and N2 (balance).