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Novel Interlayer on the Separator with the Cr3C2 Compound as a Robust Polysulfide Anchor for Lithium–Sulfur Batteries
journal contribution
posted on 2020-03-31, 15:41 authored by Xiaohong Liu, Guilin Feng, Yongchun Li, Chunliu Xu, Qi Pan, Zhenguo Wu, Benhe Zhong, Xiaodong Guo, Shuaihua Zhang, Xingtao XuThe
modification of separators with transition metal compounds
is an effective strategy to alleviate the shuttle effect of polysulfides
in lithium–sulfur (Li–S) batteries. Herein, a novel
interlayer on the separator was designed and prepared by employing
Cr-based compounds (Cr2O3 and Cr3C2), favorable sulfur host materials, as a polysulfide
anchor for promoting rate capability and cycling life. Thanks to its
specific bonding in the crystal structure, enhanced lithium-ion diffusion
dynamics, and better confine function with soluble polysulfides, the
Cr3C2-modified separator exhibits an improved
electrochemical performance as compared to the Cr2O3-modified separator, including a high capacity of 544 mA h
g–1 at 5 C, a good capacity retention ratio of about
53.3%, and excellent cycling stability with a low decay rate of 0.063%
per cycle at 3 C. It is believed that the positive outcomes will shed
light on carbide as a potential competitor for adsorbing polysulfides,
as well as supply a facile and effective avenue for expediting practical
applications of Li–S batteries.
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cycling lifepolysulfide anchordecay rateshuttle effectrate capabilityelectrochemical performanceCr 2 O 3Novel InterlayerCr 3 C 2transition metal compoundscapacity retention ratioadsorbing polysulfidesCr-based compounds3 Cbatterie5 CRobust Polysulfide Anchorcrystal structurecycling stabilityLinovel interlayersulfur host materialsseparator exhibitslithium-ion diffusion dynamics
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