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Non-cyclopentadienyl Titanium(III)−Magnesium Hydride Formation by Reduction of an Amidotitanium(IV) Complex

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posted on 2003-10-27, 00:00 authored by Q. Folashade Mokuolu, Paul A. Duckmanton, Alexander J. Blake, Claire Wilson, Jason B. Love
The reduction of an arylamido-based titanium(IV) chloride by magnesium has resulted in the formation of a unique, non-cyclopentadienyl titanium(III)−magnesium hydride with the concomitant intramolecular metalation of the arylamido ligands.

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