cm8b05047_si_001.pdf (961.19 kB)
Multiple Fused Ring-Based Near-Infrared Nonfullerene Acceptors with an Interpenetrated Charge-Transfer Network
journal contribution
posted on 2019-02-12, 15:37 authored by Jianfei Qu, Qiaoqiao Zhao, Jiadong Zhou, Hanjian Lai, Tao Liu, Duning Li, Wei Chen, Zengqi Xie, Feng HeTwo
small molecule acceptors with chlorinated IC as end groups
and 10-ring- and 12-ring-fused cores as central units, named R10-4Cl
and R12-4Cl, were designed and synthesized, which exhibit low optical
band gaps of 1.43 and 1.35 eV, respectively. X-ray crystallographic
analysis of R10-4Cl shows that the end groups of adjacent molecules
are parallel and partially overlap with a short π–π
distance of 3.32 Å, which is helpful for electron transport in
this direction. At the same time, there is another type of molecular
orientation that lies in these two molecules with an angle about 64.7°
because of the close contact of S···O with a distance
of 3.15 Å. The two types of molecular arrangements result in
an interpenetrated network structure in R10-4Cl films, which is helpful
for the rapid charge transfer either along the horizontal direction
or the sloping direction. After blending with a PBDB-T polymer donor,
the R10-4Cl-based device shows wide photocurrent response from the
visible to near-infrared regions, resulting in the better usage of
the sunlight source. Benefited from this comprehensive solar energy
absorption and the interpenetrated charge transfer, the R10-4Cl-based
devices show a power conversion up to 10.7% with an improved JSC of 18.9 mA cm–2.