jo302820m_si_002.cif (11.33 kB)

Monoimine Derived from trans-1,2-Diaminocyclohexane and Ethyl Glyoxylate: An Intermediate in Aza-Diels–Alder and Mannich Reactions

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posted on 2013-03-15, 00:00 authored by Elżbieta Wojaczyńska, Julia Bąkowicz, Mateusz Dorsz, Jacek Skarżewski

Novel enantiopure policyclic nitrogen heterocycles have been obtained in the diastereoselective aza-Diels–Alder or Mannich reaction of dienes with imine formed in situ from ethyl glyoxylate and (1R,2R)-diaminocyclohexane.

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Keywords

diastereoselective diene Intermediate Mannich ReactionsNovel enantiopure policyclic nitrogen heterocycles Mannich reaction Ethyl Glyoxylate Monoimine Derived ethyl glyoxylate tran

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