jo302820m_si_002.cif (11.33 kB)

Monoimine Derived from trans-1,2-Diaminocyclohexane and Ethyl Glyoxylate: An Intermediate in Aza-Diels–Alder and Mannich Reactions

Download (11.33 kB)
dataset
posted on 15.03.2013 by Elżbieta Wojaczyńska, Julia Bąkowicz, Mateusz Dorsz, Jacek Skarżewski
Novel enantiopure policyclic nitrogen heterocycles have been obtained in the diastereoselective aza-Diels–Alder or Mannich reaction of dienes with imine formed in situ from ethyl glyoxylate and (1R,2R)-diaminocyclohexane.

History

Exports