ma7b01524_si_001.pdf (1.35 MB)
Modulation of Majority Charge Carrier from Hole to Electron by Incorporation of Cyano Groups in Diketopyrrolopyrrole-Based Polymers
journal contribution
posted on 2017-09-26, 00:00 authored by Hee Su Kim, Gunel Huseynova, Yong-Young Noh, Do-Hoon HwangA thienylene–vinylene–thienylene
(TVT) derivative
with cyano groups in the 3- and 3′-positions was synthesized
as a building block of semiconducting polymers for high mobility organic
field effect transistors (OFETs). (E)-1,2-Di-(3-cyanothiophen-2-yl)ethene
(2CNTVT) was copolymerized with diketopyrrolopyrrole (DPP) units via
Stille coupling reaction to give 2DPP-2CNTVT and 7DPP-2CNTVT. The
properties of these two polymers were compared with those of the corresponding
polymers without cyano groups in TVT (2DPP-TVT and 7DPP-TVT). The
effects of CN groups and branched alkyl position were found to have
a significant influence on the optical, electrochemical, morphological,
and charge transporting properties of the polymers. The average hole
mobilities of OFETs fabricated with 2DPP-TVT and 7DPP-TVT OFETs were
1.63 and 2.2 cm2 V–1 s–1, respectively, and the average electron mobility for both 2DPP-2CNTVT
and 7DPP-2CNTVT OFETs was 1.2 cm2 V–1 s–1.