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Microkinetic Modeling of HC-SCR of NO to N2, N2O, and NO2 on Pt Catalysts in Automotive Aftertreatment
journal contribution
posted on 2017-09-25, 00:00 authored by Vishnu
S. Prasad, Preeti AghalayamOne of the main pollutants in automobile
engine exhausts is NO.
Hydrocarbon-based selective catalytic reduction (HC-SCR) is one of
the most preferred methods to reduce NO at the expense of unburned
hydrocarbons, which are also present in automobile exhausts. In this
study, we have developed a detailed kinetic model and analyzed the
selectivity of NO reduction to various products (N2, N2O, and NO2). The optimal operating conditions for
the maximum reduction of NO to N2 are also explored. Various
phenomena including coking and the oxygen-rich nature of the catalyst
surface are found to occur as the amount of oxygen in the inlet is
varied. The influence of O2 and temperatures on the selectivity
of NO reduction is discussed in detail.