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Micellization and Adsorption Properties of New Cationic Gemini Surfactants Having Hydroxyisopropyl Group
journal contribution
posted on 2019-02-20, 18:15 authored by Ziyafaddin
H. Asadov, Gulnara A. Ahmadova, Ravan A. Rahimov, Seyid-Zeynab F. Hashimzade, Etibar H. Ismailov, Nahida Z. Asadova, Samira A. Suleymanova, Fedor I. Zubkov, Ayaz M. Mammadov, Durna B. AgamaliyevaA series
of cationic gemini surfactants, N,N′-bis(alkyl)-N,N′-bis(2-hydroxypropyl)ethylenediammonium
dibromide, [CnH2n+1(CH3CH(OH)CH2)NH(CH2)2NH(CH2CH(OH)CH3)CnH2n+1]Br2 (where n is the
tail chain length, n = 9, 12, and 14), referred to
as CnC2Cn[iso-Pr(OH)] was synthesized. Via conductometric and tensiometric
methods, at different temperatures (283 to 313 K), specific electrical
conductivities and surface tensions of the aqueous solutions of these
cationic gemini surfactants were determined. According to the obtained
values, micellization and adsorption parameters such as critical micellization
concentration (CMC), maximum surface excess (Γmax), minimal cross sectional surface area of surfactant polar group
(Amin), adsorption efficiency (pC20), surface pressure (π), and binding degree of counterion
(β) were calculated. The values of standard Gibbs free energy
(ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were also
computed. Via the dynamic light scattering method, diameters of aggregates
of the synthesized cationic gemini surfactants were determined in
water. It was established that the diameters of these aggregates decrease
with a temperature rise. Antibacterial properties of the synthesized
cationic surfactants against sulfate-reducing bacteria (SRB) were
studied.
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surface areasurface tensionsaggregates decreaseHydroxyisopropyl GroupCMCmicellization concentrationC n C 2 C nadsorption parameterscationic surfactantsdiametertemperature riseNHbinding degreetensiometric methodsSRBCHcationic gemini surfactantsAdsorption PropertiesNew Cationic Gemini SurfactantsVia conductometricAntibacterial propertiessulfate-reducing bacteriatail chain length
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