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Manganese(III)-Mediated Selective Diphenylphosphinoyl Radical Reaction of 1,4-Diaryl-1-butynes for the Synthesis of 2‑Phosphinoylated 3,4-Dihydronaphathalenes

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posted on 2014-02-21, 00:00 authored by Da-Peng Li, Xiang-Qiang Pan, Li-Tao An, Jian-Ping Zou, Wei Zhang
A diphenylphosphinoyl radical-initiated sequential reaction of 1,4-diaryl-1-butynes and analogues is developed for the synthesis of 2-phosphinoylated 3,4-dihydronaphathalenes and related compounds.

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