Isolation of Bis(η2-nitrato)(η4-cyclobutadiene)cobalt(II) Complexes from the Oxidation of Sterically Hindered CpCo-Stabilized Cyclobutadiene Complexes
2004-05-10T00:00:00Z (GMT)
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The oxidation of sterically hindered, CpCo-protected cyclobutadienes with ceric ammonium nitrate
(CAN) yielded the paramagnetic Co(NO3)2-protected
cyclobutadiene products. These half-sandwich complexes
represent possible intermediates within the mechanism
of the CAN decomplexation of CpCo−cyclobutadiene
complexes.
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