Isolable Zwitterionic Pyridinio-semiquinone π-Radicals. Mild and Efficient Single-Step Access to Stable Radicals
2009-06-04T00:00:00Z (GMT) by
A rational design based on the proton-coupled electron transfer (PCET) concept allows us to structurally characterize for the first time isolable, air- and moisture-stable semiquinone radicals in a zwitterionic neutral form. The presence of an alkoxy and the bulky pyridinio substituents causes only a minor perturbation of either the redox potentials or the spectral UV−vis characteristics of the semiquinone core but significantly stabilizes the new radicals.