ja077322o_si_003.pdf (142.58 kB)
Infrared Spectra of the WH4(H2)4 Complex in Solid Hydrogen
journal contribution
posted on 2008-02-13, 00:00 authored by Xuefeng Wang, Lester Andrews, Ivan Infante, Laura GagliardiThe codeposition of laser-ablated tungsten atoms with neat hydrogen at 4 K forms a single
major product with a broad 2500 cm-1 and sharp 1860, 1830, 1782, 1008, 551, and 437 cm-1 absorptions,
which are assigned to the WH4(H2)4 complex on the basis of isotopic shifts and agreement with isotopic
frequencies calculated by density functional theory. This D2d structured complex was computed earlier to
form exothermically from W atoms and hydrogen molecules. Annealing the matrix allows hydrogen to
evaporate and the complex to aggregate and ultimately to decompose. Comparison of the H−H stretching
mode at 2500 cm-1 and the W−H2 stretching mode at 1782 cm-1 with 2690 and 1570 cm-1 values for the
Kubas complex W(CO)3(PR3)2(H2) suggests that the present physically stable WH4(H2)4 complex has more
strongly bound dihydrogen ligands. Our CASPT2 calculations suggest a 15 kcal/mol average binding energy
per dihydrogen molecule in the WH4(H2)4 complex.