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Highly Efficient Blue Electrophosphorescent Polymers with Fluorinated Poly(arylene ether phosphine oxide) as Backbone
journal contribution
posted on 2016-02-20, 11:16 authored by Shiyang Shao, Junqiao Ding, Lixiang Wang, Xiabin Jing, Fosong WangIn view of the tolerance of F atoms in FIrpic to the
nucleophilic
aromatic substitution polymerization, an activated fluorinated poly(arylene
ether phosphine oxide) backbone is used to construct novel blue electrophosphorescent
polymers containing FIrpic as the blue emitter, because they can be
synthesized under a milder temperature of 120 °C. Compared with
the counterparts prepared at high temperature (165 °C), unexpected
bathochromic shift is successfully avoided, and a state-of-art luminous
efficiency as high as 19.4 cd A–1 is achieved. The
efficiency is comparable to the corresponding physical blend system,
which indicates that the fluorinated poly(arylene ether phosphine
oxide) has the potential to be used as the platform for the development
of high-performance all-phosphorescent white polymer based on single
polymer system.