Harvesting the Strain Installed by a Paternò−Büchi Step in a Synthetically Useful Way: High-Yielding Photoprotolytic Oxametathesis in Polycyclic Systems

2009-09-03T00:00:00Z (GMT) by Roman A. Valiulin Andrei G. Kutateladze
High-yielding one-pot photoinduced transformation of readily available endoaroyl and heteroaroyl Diels−Alder adducts into novel polycyclic aldehydes or their hemiacetals, decorated by carbo- and heterocyclic pendants, is described.