ol901456m_si_003.cif (14.25 kB)

Harvesting the Strain Installed by a Paternò−Büchi Step in a Synthetically Useful Way: High-Yielding Photoprotolytic Oxametathesis in Polycyclic Systems

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posted on 2009-09-03, 00:00 authored by Roman A. Valiulin, Andrei G. Kutateladze

High-yielding one-pot photoinduced transformation of readily available endoaroyl and heteroaroyl Diels−Alder adducts into novel polycyclic aldehydes or their hemiacetals, decorated by carbo- and heterocyclic pendants, is described.

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Keywords

adduct Oxametathesi endoaroyl heterocyclic pendants Harvesting novel polycyclic aldehydes Synthetically Useful Way Paterno Diel transformation Polycyclic Systems photoinduced hemiacetal Photoprotolytic heteroaroyl Strain carbo

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