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Gold Nanoparticles Located at the Interface of Anatase/Rutile TiO2 Particles as Active Plasmonic Photocatalysts for Aerobic Oxidation
journal contribution
posted on 2012-04-11, 00:00 authored by Daijiro Tsukamoto, Yasuhiro Shiraishi, Yoshitsune Sugano, Satoshi Ichikawa, Shunsuke Tanaka, Takayuki HiraiVisible-light irradiation (λ > 450 nm) of gold
nanoparticles
loaded on a mixture of anatase/rutile TiO2 particles (Degussa,
P25) promotes efficient aerobic oxidation at room temperature. The
photocatalytic activity critically depends on the catalyst architecture:
Au particles with <5 nm diameter located at the interface of anatase/rutile
TiO2 particles behave as the active sites for reaction.
This photocatalysis is promoted via plasmon activation of the Au particles
by visible light followed by consecutive electron transfer in the
Au/rutile/anatase contact site. The activated Au particles transfer
their conduction electrons to rutile and then to adjacent anatase
TiO2. This catalyzes the oxidation of substrates by the
positively charged Au particles along with reduction of O2 by the conduction band electrons on the surface of anatase TiO2. This plasmonic photocatalysis is successfully promoted by
sunlight exposure and enables efficient and selective aerobic oxidation
of alcohols at ambient temperature.
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catalyst architectureplasmonic photocatalysisgold nanoparticlesanatase TiO 2.gold Nanoparticlesparticles transfersunlight exposureoxidationconduction electronsambient temperaturephotocatalytic activityconduction band electronsO 2electron transferActive Plasmonic Photocatalysts450 nmroom temperatureplasmon activation
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