posted on 2020-03-19, 15:33authored byGilles
H. Timmermans, Maxime van der Heijden, Bernette M. Oosterlaken, Stefan C. J. Meskers, Albert P. H. J. Schenning, Michael G. Debije
Förster resonance
energy transfer (FRET) is important, not
only in the fields of biology and biophysics but also in optoelectronics
and light guiding systems. Different matrixes are being investigated
that facilitate FRET, including zeolites and metal–organic
frameworks. In this work, a matrix for FRET generation is proposed:
nanoporous liquid crystal networks. These liquid crystal networks
can be easily processed and can align dichroic fluorescent dyes. A
base treatment can create nanopores in the network, which are then
able to absorb a second fluorescent dye in an aqueous phase while
still retaining good alignment. Using lifetime measurements, we provide
proof that even in this nonoptimized system, around 70% of the energy
was transferred via the FRET mechanism from one dye to the other.
Liquid crystal networks have many advantages over current matrixes
as they are easy to fabricate as well as flexible and could be modified
to selectively and reversely absorb dyes, allowing many applications.