ic7b00304_si_001.pdf (1.56 MB)
Fe3O4/FeNi Embedded Nanostructure and Its Kinetic Law for Selective Catalytic Reduction of p‑Nitrophenyl Compounds
journal contribution
posted on 2017-04-20, 16:04 authored by Dandan Wu, Yanqiao Zhang, Ming Wen, Hao Fang, Qingsheng WuTo meet the requirement
of high catalytic efficiency toward the reduction of p-nitrophenyl compounds, we designed a new one-dimensional Fe3O4/FeNi embedded-nanostructured catalyst synthesized
by a one-pot controlling-growth-reduction process in a solvothermal
system, in which Fe3O4 phase was implanted in
the base of FeNi alloy. In the Fe3O4/FeNi catalyst
system, the Fe3O4 embedded phase attracts the
nitro group of p-nitrophenyl compounds by its high-density
electrons, which can efficiently promote the activity of amorphous
FeNi active centers for selective catalysis toward the reduction of
a range of p-nitrophenyl compounds. Moreover, for
the para-group in the nitrophenyl compounds, an increasing electron-donating
power contributes to a higher catalytic activity, while electron-withdrawing
power obtains the reverse case. Additionally, the Fe3O4/FeNi composite nanocatalyst exhibited an outstanding cycling
performance over 20 times without obvious performance decay. This
work opens an avenue to design more powerful non-noble metal catalysts
for green chemistry.