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Factors Influencing the Time-Resolved Evolution of NO, HCN, and N2O during Char Oxidation at Fluidized Bed Conditions
journal contribution
posted on 2002-04-17, 00:00 authored by Shakti Goel, Alejandro Molina, Adel F. SarofimThere is increasing evidence that HCN is an important intermediate to the production of N2O
during the oxidation of char nitrogen at fluidized bed combustion conditions. The experimental
evidence shows that N2O is formed primarily during oxidation so that the fundamental question
is on which fuel N intermediate is formed during char consumption. This paper models first the
conversion of char nitrogen assumed to be released as HCN, simulating the homogeneous nitrogen
chemistry in the boundary layer of a single char particle. This pathway, which is based on 180
reversible gas-phase reactions and 33 chemical species, assumes that HCN is released at a rate
proportional to carbon consumption. The oxidation of HCN occurs in the boundary layer of the
particle. An alternative pathway assumes that during oxidation, NO is formed in addition to a
cyano species by heterogeneous processes and then both NO and the cyano species react in the
boundary layer. The temporal evolution of NO, N2O, and cyano compounds from both models
have been compared against the observations obtained at fluidized bed conditions. The results
suggest that solely HCN oxidation on the boundary layer does not predict the most important
trends observed for the production of NO and N2O for char oxidation at fluidized bed combustion
conditions. On the contrary, the simultaneous heterogeneous production of NO and a cyano-like
species can predict to a certain extent the experimental observations but will require a more
detailed understanding of the surface chemistry which controls the temporal evolution of NO
and cyano species.