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Facile and Green Synthesis of Carboxylated Cellulose Nanocrystals as Efficient Adsorbents in Wastewater Treatments
journal contribution
posted on 2019-10-18, 19:46 authored by Xue-Meng Fan, Hou-Yong Yu, Duan-Chao Wang, Zhong-Hao Mao, Juming Yao, Kam Chiu TamA simple
and eco-friendly Fe2+/H2O2 oxidation
of microcrystalline celluloses (MCCs) to prepare cellulose
nanocrystals (CNCs) with high carboxylation content is proposed. The
effects of reaction times on the morphology, microstructure, and chemical
and thermal properties of isolated carboxylated CNCs were investigated.
The oxidative decomposition of Fe2+/H2O2 solution of MCC yielded CNCs with a size of 92–140
nm in length and 19–23 nm in width. The CNCs extracted at 6
h possessed the highest carboxyl content (2.2 mmol/g) with a zeta
potential of −41 mV and a thermal decomposition temperature
of greater than 325 °C. These CNCs are efficient adsorbents for
dyes (methylene blue) and metal ions (copper ion) found in wastewater,
with removal rates of up to 95.6 and 82.3%, respectively.