sc8b00776_si_001.pdf (521.53 kB)
Facile Synthesis of FeOOH Quantum Dots Modified ZnO Nanorods Films via a Metal-Solating Process
journal contribution
posted on 2018-05-02, 00:00 authored by Faqi Zhan, Yahui Yang, Wenhua Liu, Keke Wang, Wenzhang Li, Jie LiIn
this study, we referenced the formation principle of rust in
nature and the FeOOH quantum dots (QDs) were prepared using a metal-solating
process. The FeOOH QDs exhibited an average diameter of 3.5 nm with
well crystallinity. Furthermore, the as-prepared FeOOH QDs were deposited
on ZnO nanorods film as a co-catalyst for water oxidation. The crystal
phase, microstructures, and optical properties of the synthesized
films were established through X-ray diffraction (XRD), scanning electron
microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy,
and ultraviolet–visible absorption spectroscopy (UV-vis). Applied
as a photoanode for solar water splitting, the FeOOH QDs/ZnO nanorods
film exhibited a photocurrent density of 0.44 mA/cm2 at
1.23 V vs RHE, which is 2.1 times higher than that of pure ZnO film.
After the loading of FeOOH QDs, the ZnO photoanode showed higher surface
charge injection efficiency (by a factor of ∼2) and better
long-term stability. The analysis of electrochemical measurements
displayed that, as a co-catalyst of the oxygen evolution reaction,
FeOOH QDs resulted in a noticeable cathodic shift of photocurrent
onset potential for water oxidation and a remarkable improvement of
surface charge injection efficiency. In addition, the metal-solating
method can be applied to preparing the other metal oxides QDs, such
as WO3 and ZnO QDs.