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Fabrication of “Zn2+ Salt-Bondings” Cross-Linked SBS‑g‑COOH/ZnO Composites: Thiol–Ene Reaction Modification of SBS, Structure, High Modulus, and Shape Memory Properties
journal contribution
posted on 2019-05-20, 13:33 authored by Mengwen Yan, Liming Cao, Chuanhui Xu, Yukun ChenThe fabrication of
SBS-g-COOH/ZnO composites cross-linked
by Zn2+ salt-bondings was reported. First, SBS-g-COOH with different grafting ratio was synthesized through
the thermally induced thiol–ene click reaction, which was corroborated
by FT-IR and 1H NMR. Next, zinc oxide (ZnO) was added to
coordinate with the carboxyl groups of SBS-g-COOH
to obtain the Zn2+ salt-bondings. TEM images, demonstrating
the ion-rich domains with size of 30–50 nm, substantiated the
formation of Zn2+ salt-bondings and also exhibited that
the size and density of ion domains increased with the increasing
content of ZnO. The salt-bondings effectively enhanced the mechanical
properties of SBS-g-COOH/ZnO composites, achieving
a maximum tensile stress of 14.24 MPa at 100% strain and a Young’s
modulus of 14.19 MPa, which were almost 4.49 times and 4.35 times
larger than that without ZnO, respectively. Simultaneously, the ionic
networks cross-linked by salt-bondings endowed the composites with
feasible shape memory behaviors that the best shape recovery ratio
could be up to 97%.