cm8b03845_si_001.pdf (1.9 MB)
Fabrication of Porous Functional Nanonetwork-Structured Polymers with Enhanced Adsorption Performance from Well-Defined Molecular Brush Building Blocks
journal contribution
posted on 2018-11-15, 18:49 authored by Guojun Xie, Xidong Lin, Michael R. Martinez, Zelin Wang, He Lou, Ruowen Fu, Dingcai Wu, Krzysztof MatyjaszewskiWe report the fabrication of porous
functional nanonetwork-structured
polymers (FNSPs) consisting of poly(acrylic acid) functional cores
surrounded by a microporous shell network, via a combination of atom
transfer radical polymerization (ATRP) and Friedel–Crafts hyper-cross-linking
chemistry. Well-defined molecular brushes with diblock poly(tert-butyl acrylate)-block-polystyrene
(PtBA-b-PS) side chains serve as
tunable building blocks to synthesize porous networks. The prepared
FNSPs demonstrated significantly enhanced adsorption toward basic
dyes, up to 767 mg g–1.
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adsorptionmicroporous shell networkFriedelFNSPdiblocktunable building blocksWell-Defined Molecular Brush Building Blocksacidtertpolymerizationnanonetwork-structured polymersdyeP t BAside chainsEnhanced Adsorption PerformanceFabricationacrylatecorecombinationPSATRPatom transferfabricationmgpolystyrenePorous Functional Nanonetwork-Structured PolymersbutylWell-definedhyper-cross-linking
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