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Fabrication of Functionalized Porous Silica Nanocapsules with a Hollow Structure for High Performance of Toluene Adsorption–Desorption
journal contribution
posted on 2020-03-11, 08:34 authored by Junjie Chen, Chao Sun, Zhen Huang, Feng Qin, Hualong Xu, Wei ShenFunctionalized
mesoporous silicas are an emerging kind of adsorbents
for the removal of volatile organic compounds (VOCs). Breaking the
limitations of traditional mesoporous silica, in this study, porous
silica nanocapsules (PSNs) functionalized with phenyl and n-octyl groups (named as p-PSN and n-PSN, respectively) were developed for the first time.
Under dry conditions, the PSNs exhibited highest dynamic adsorption
capacity and desorption efficiency among the ever-reported typical
adsorbents (i.e., SBA-15, KIT-6, silicalite-1, and activated carbon).
Under wet conditions, the functionalized PSNs made up the defects
of pure PSNs, displaying excellent hydrophobicity. The QWET for n-PSN and p-PSN
increased by 44 and 76%, respectively, as compared with that of pure
PSNs in 50% relative humidity. The Henry constant of static adsorption
demonstrated that p-PSN had a better capture ability
for toluene, which was owing to the π-interaction between the
phenyl groups and the toluene molecules. In addition, p-PSN showed considerable stability after six consecutive dynamic
adsorption–desorption cycles in 50% relative humidity.