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Exceptional Steric Congestion in an in,in-Bis(hydrosilane)

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posted on 2013-09-11, 00:00 authored by Jie Zong, Joel T. Mague, Robert A. Pascal
The synthesis and characterization of a macrobicyclic in,in-bis­(hydrosilane) is described. A combination of crystallographic and computational data indicate that the central hydrogen–hydrogen nonbonded contact distance is the shortest for any crystallographically characterized compound.

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