ja407398w_si_002.cif (22.05 kB)
Exceptional Steric Congestion in an in,in-Bis(hydrosilane)
dataset
posted on 2013-09-11, 00:00 authored by Jie Zong, Joel T. Mague, Robert A. PascalThe synthesis and
characterization of a macrobicyclic in,in-bis(hydrosilane) is described. A combination
of crystallographic and computational data indicate that the central
hydrogen–hydrogen nonbonded contact distance is the shortest
for any crystallographically characterized compound.