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Evolving Crystal Morphology of Potassium Chloride Controlled by Optical Trapping
journal contribution
posted on 2020-03-13, 14:14 authored by An-Chieh Cheng, Hiroshi Masuhara, Teruki SugiyamaDynamic morphology
evolution of potassium chloride (KCl) crystals was demonstrated by
surface optical trapping with a focused continuous-wave near-infrared
laser. Optical trapping at an air/solution interface triggered the
crystallization, and then, the dynamic change in crystal morphology
was observed in real time. We observed three different crystal morphologies
of needle, rectangle, and cubic at the early stage of crystallization.
As the laser power increases, the probability of generation of a cubic
crystal increases, especially upon the irradiation with linear polarization.
We also found laser polarization-dependent morphology evolution by
the continuous irradiation to the generated crystals. Upon linearly
polarized laser irradiation, the stepwise morphology evolves from
needle to rectangle, and eventually to cubic, which is an equilibrium
shape of KCl crystals. Meanwhile, circularly polarized laser irradiation only induced morphology
evolution from needle to rectangle, without morphology change into
cubic, because the rectangle crystal was dissolved while the crystal
was rotating. It was made possible to observe such a unique morphological
evolution due to the spatiotemporal controllability of our crystallization
method. The dynamics and mechanism of these intriguing phenomena are
discussed from the perspective of a dense cluster domain formed by
optical trapping before nucleation.