cg4013685_si_001.pdf (13.74 MB)
Enhancing Strategies for the Assembly of Metal–Organic Systems with Inherent Cavity-Containing Calix[4]arenes
journal contribution
posted on 2013-12-04, 00:00 authored by Piotr
P. Cholewa, Christine M. Beavers, Simon J. Teat, Scott J. Dalgarnop-Carboxylatocalix[4]arenes have recently emerged
as useful building blocks in the assembly of both discrete and polymeric
coordination compounds. Steric effects of coligands used are now shown
to dramatically influence the assembly process, dictating the assembly
of one-dimensional (1D)-three-dimensional (3D) systems. Solvothermal
techniques have also been found to promote formation of 3D systems
with a sterically undemanding coligand.