am201301u_si_001.pdf (289.36 kB)
Effects of Side-Chain Interdigitation on Stability: An Environmentally, Electrically, and Thermally Stable Semiconducting Polymer
journal contribution
posted on 2016-02-22, 05:06 authored by Danbi Choi, Ban-Seok Jeong, Byungcheol Ahn, Dae Sung Chung, Kimin Lim, Se Hyun Kim, Seon Uk Park, Moonhor Ree, Jaejung Ko, Chan Eon ParkA polymeric semiconductor, poly(3,6-dihexyl-[2,2′]bi[thieno[3,2-b]thiophene])
(PDHTT), was synthesized and tested as an active layer in organic
thin film transistors (OTFTs). This semiconductor showed considerable
potential for use in commercial electronic devices because of its
superior characteristics, particularly its good stability. PDHTT-based
OTFTs exhibited high stability in air, retaining their initial performance
after exposure to 70% relative humidity for 50 days; they were also
stable under repeated electrical stress and even after exposure to
temperatures as high as 250 °C. We attribute the remarkable stability
of PDHTT OTFTs to the relatively low highest occupied molecular orbital
(5.1 eV) level of the polymer and its highly interdigitated structure
in the thin film state.