la8b04278_si_001.pdf (1.76 MB)
Effect of Aggregation and Adsorption Behavior on the Flow Resistance of Surfactant Fluid on Smooth and Rough Surfaces: A Many-Body Dissipative Particle Dynamics Study
journal contribution
posted on 2019-05-10, 00:00 authored by Peng Zhou, Jian Hou, Youguo Yan, Jiqian Wang, Wei ChenTo study the effect of surfactant
on the resistance of wall-bound
flow, the adsorption and aggregation behaviors of surfactant fluid
on both smooth and groove-patterned rough surface are investigated
through many-body dissipative particle dynamics (MDPD) simulation.
The MDPD models of surfactants were carefully parametrized and have
been validated to be able to simulate the aggregation and adsorption
behavior of surfactants. The simulation results show that the surfactant
in laminar flow can only increase the flow resistance on the smooth
surface. On the rough surface, surfactant with strong adsorption performance
on the channel wall shows a drag reduction effect at moderate concentration.
The surfactant with weak adsorption properties can enhance the flow
resistance, which is even more significant than that of those surfactants
with no adsorption capacity. Although heating (high temperature) can
generally reduce the viscosity and flow resistance of surfactant fluid,
it would cause a poor drag reduction efficiency. It may arise from
the destruction of the adsorption layer and the interruption of the
fluid/boundary interface. Surfactant adsorption can tune the roughness
of the fluid boundary on either the smooth or rough surface in a different
manner, which turns out to be highly correlated to the change in flow
resistance. Compared with the adsorption layer, surfactant in the
bulk fluid makes a greater contribution to enhancing the flow resistance
as the concentration rises. This study is expected to be helpful in
guiding the application of surfactants on the micro- and nanoscale
such as lab-on-a-chip nanodevices and EOR in a low-permeability porous
medium.