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Direct Valorization of Lignocellulosic Biomass into Value-Added Chemicals by Polyoxometalate Catalyzed Oxidation under Mild Conditions
journal contribution
posted on 2019-12-13, 19:18 authored by Weisheng Yang, Xu Du, Wei Liu, Zewei Wang, Hongqi Dai, Yulin DengEfficient methodologies for converting sustainable lignocellulosic
biomass to high-value chemicals are important for the utilization
of biomass. Although many conversion methods have been proposed, those
that are commonly used require harsh operating conditions. Polyoxometalate
(POM) can be used either as a direct oxidation agent or as a catalyst
to depolymerize technical lignin, but the lignin oil yield for this
process is relatively low. Instead of using technical lignin, in this
study we used an oxidation approach to directly convert native lignocellulose
in a methanol/water mixture using polyoxometalate (H3PMo12O40) as a catalyst to produce high-value chemicals.
80% of lignin in the hardwood was depolymerized to low molecular weight
lignin oil (376 Da) at 150 °C and 1 MPa O2 in 2 h.
The lignin oil yielded 38.0% aromatic monomers, based on total lignin
mass. Simultaneously, only 9.2% residual solids remained; 83.7% of
the hemicellulose in the hardwood was converted to water-soluble carbohydrates.