jz7b00482_si_003.avi (560.81 kB)
Direct Observation of Charge Collection at Nanometer-Scale Iodide-Rich Perovskites during Halide Exchange Reaction on CH3NH3PbBr3
media
posted on 2017-03-31, 00:00 authored by Izuru Karimata, Yasuhiro Kobori, Takashi TachikawaOrganolead halide
perovskites MAPbX3 (MA = CH3NH3+, X = Cl–, Br–, or I–) are known to undergo reversible halide
exchange reactions, enabling bandgap tuning over the visible light
region. Using single-particle photoluminescence (PL) imaging for in
situ observation, we have studied the structure-dependent charge dynamics
during halide exchange with iodide ions on an MAPbBr3 crystal.
In particular, we optically detected nanometer-scale iodide-rich domains
(i.e., MAPbBrI2) and found that their lifetimes of several
tens of milliseconds are limited by reaction with diffusing vacancies.
Furthermore, it was discovered that these domains effectively collect
the charge carriers from the bulk crystal, thus resulting in amplified
spontaneous emission (ASE) under continuous-wave laser irradiation.
Our findings will provide direction for development of perovskite
heterostructures with enhanced charge utilization.
History
Usage metrics
Categories
Keywords
halide exchangeperovskite heterostructuresNanometer-Scale Iodide-Rich Perovskitesiodide ionsDirect ObservationASElight regionsingle-particle photoluminescencebulk crystalMAPbBr 3 crystalPLHalide Exchange Reactioncharge utilizationCH 3 NH 3 PbBr 3 Organolead halide perovskites MAPbX 3nanometer-scale iodide-rich domainsstructure-dependent charge dynamicsCharge Collectioncontinuous-wave laser irradiationcharge carriershalide exchange reactionsCH 3 NH 3
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC