ic402155h_si_002.cif (92.62 kB)
Dimeric and Tetrameric Supramolecular Aggregates of Single-Molecule Magnets via Carboxylate Substitution
dataset
posted on 2013-11-04, 00:00 authored by Andrew M. Mowson, Tu N. Nguyen, Khalil A. Abboud, George Christou[Mn3]2 and [Mn3]4 supramolecular
aggregates of weakly exchange-coupled MnIII3 single-molecule magnets (SMMs) with S = 6 have
been prepared by carboxylate substitution on [Mn3O(O2CMe)3(mpko)3]+ [mpkoH = methyl(pyridine-2-yl)
ketone oxime)] with the dicarboxylic acids α-truxillic acid
and fumaric acid, respectively. The method opens up a new approach
to Mn3 SMM aggregates of various size and topology.
