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Dicyanovinylene and Thiazolo[5,4‑d]thiazole Core Containing D–A–D Type Hole-Transporting Materials for Spiro-OMeTAD-Free Perovskite Solar Cell Applications with Superior Atmospheric Stability
journal contribution
posted on 2019-10-17, 18:48 authored by Govindasamy Sathiyan, Rahul Ranjan, Sudhir Ranjan, Ashish Garg, Raju Kumar Gupta, Anand SinghIn
perovskite solar cell (PSC) devices, hole-transporting materials
(HTMs) are vital components affecting the charge separation and playing
an important role in achieving high efficiencies. These may also protect
active light-absorbing layers from degradation. The current best-in-class
HTM Spiro-OMeTAD is prohibitively expensive for large-scale applications,
and hence, design of novel cost-effective HTMs yielding comparable
device performance is essential. In this paper, we report synthesis
of donor–acceptor–donor (D–A–D) type hole-transporting
materials (TTz-1 and TPDCN) featuring the dicyanovinylene and thiazolo[5,4-d]thiazole cores and evaluate their performance via integrating
them in perovskite solar cells
(PSCs). The results suggest that both the HTMs are easy to synthesize
and demonstrate favorable structural characteristics for device integration.
Detailed analysis reveals that the molecules show appropriate energy
level alignment with methylammonium lead iodide (CH3NH3PbI3) perovskite and possess good thermal stability
and high hole mobility. Planar PSC devices fabricated using TTz-1
as an HTM yielded a power conversion efficiency (PCE) of 11.37%, while
devices using TPDCN show a PCE of 10.11%, comparable to the PCE of
11.62% obtained in control samples based on Spiro-OMeTAD. In addition,
stability analysis of the devices shows that devices fabricated using
TTz-1 and TPDCN exhibit superior atmospheric stability as compared
to those based on Spiro-OMeTAD. These results suggest that the reported
HTM architectures are promising leads for designing new HTMs for perovskite
solar cells owing to their simple and scalable synthesis and tunability.
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Planar PSC devicesbest-in-class HTM Spiro-OMeTADreport synthesisdevice performancepower conversion efficiencyPCEenergy level alignmentSuperior Atmospheric StabilitySpiro-OMeTAD-Free Perovskite Solar Cell ApplicationsTTzdevice integrationTPDCN exhibithole mobilitycharge separationscalable synthesishole-transporting materialscontrol samplesmolecules showperovskiteCH 3 NH 3 PbI 3stability analysislight-absorbing layersHTM architecturesTPDCN show
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