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Development of Latent Fingerprints via Aryldiazonium Tetrachloroaurate Salts on Copper Surfaces: An XPS Study
journal contribution
posted on 2019-12-12, 22:04 authored by Saeed Almheiri, Ahmad A. L. Ahmad, Benjamin Le Droumaguet, Rémy Pires, Ahmed A. Mohamed, Mohamed M. ChehimiSurface studies of developed fingerprints have aided
in the elimination
of criminal cases before moving to the court. The combination of X-ray
photoelectron spectroscopy (XPS) with the aryldiazonium gold(III),
4-O2NC6H4N2+AuCl4–, surface modifier has been shown
to be a novel approach in latent fingerprint detection and development
for the quantification of film elements. The robust gold–aryl
film was developed on the reducing chemicals excreted in the sebaceous
fingerprints without the need for external stimuli and at a lesser
extent after contacting the free metal surface. The concurrent reduction
of the diazonium functional group and gold(III) from [AuCl4]‑ developed a robust gold–aryl film, which
showed increasing gold(0) quantity in the time range of 30–120
min over copper coins and model flat sheets. Scanning electron microscopy
(SEM) and X-ray diffraction (XRD) support the presence of reduced
gold on the top of the latent fingerprints and the presence of CuO
resulting from the reaction of the diazonium salt with copper metal.
This research combines the quantification of deposits using XPS, a
surface-sensitive technique for chemical analysis, in addition to
surface imaging.
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Keywords
fingerprint detectionScanning electron microscopychemical analysisAuCl 4surface imagingfilm elementsX-ray diffractionAryldiazonium Tetrachloroaurate SaltsXPS Study Surface studiesXRDX-ray photoelectron spectroscopymetal surfacetime rangediazonium saltNCLatent FingerprintsSEMCopper Surfacessurface-sensitive techniquecopper metalnovel approachsurface modifiercopper coinssebaceous fingerprints
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