ma7b01613_si_001.pdf (1.77 MB)
Development of Highly Crystalline Donor–Acceptor-Type Random Polymers for High Performance Large-Area Organic Solar Cells
journal contribution
posted on 2017-09-26, 18:21 authored by Jae Hoon Yun, Hyungju Ahn, Phillip Lee, Min Jae Ko, Hae Jung SonWe developed donor–acceptor
(D–A)-type random polymers
based on 3,3′-difluoro-2,2′-bithiophene with various
relative amounts of 5,6-difluoro-4,7-bis(5-bromo-(2-decyltetradecyl)thiophen-2-yl)-2,1,3-benzothiadiazole
(2FBT) and 5,6-difluoro-4,7-bis(5-bromo-(2-octyldodecyl)thiophen-2-yl)-2-(3,4-dichlorobenzyloxybutyl)-2H-benzo[d][1,2,3]triazole (DCB-2FBTZ).
Introducing small relative amounts of DCB-2FBTZ into the polymer was
found to effectively enhance its solar cell performance, resulting
in a power conversion efficiency of 9.02%, greater than the 7.29%
that resulted from the PFBT-FTh copolymer. Moreover, when the active
area of the BHJ film was increased to 1 cm2, the solar
cell reproducibly showed a high performance, here with an efficiency
of 8.01% even when the thickness of the active layer was 313 nm. Our
studies revealed that including the DCB-2FBTZ group in the polymer
simultaneously improved the solution processability and crystallinity
of the polymer. These improvements resulted in the formation of highly
homogeneous BHJ films throughout large areas with only minor amounts
of defects resulting from overaggregation and hence with appropriate
morphologies for effective charge generation and transport.