ac203006j_si_001.pdf (196.94 kB)
Determination of the Atomic Weight of 28Si-Enriched Silicon for a Revised Estimate of the Avogadro Constant
journal contribution
posted on 2012-03-06, 00:00 authored by Lu Yang, Zoltán Mester, Ralph
E. Sturgeon, Juris MeijaThe much anticipated overhaul of the International System
of Units (SI) will result in new definitions of base units in terms
of fundamental constants. However, redefinition of the kilogram in
terms of the Planck constant (h) cannot proceed without
consistency between the Avogadro and Planck constants, which are both
related through the Rydberg constant. In this work, an independent
assessment of the atomic weight of silicon in a highly enriched 28Si crystal supplied by the International Avogadro Coordination
(IAC) was performed. This recent analytical approach, based on dissolution
with NaOH and its isotopic characterization by multicollector inductively
coupled plasma mass spectrometry, is critically evaluated. The resultant
atomic weight Ar(Si) = 27.976 968 39(24)k=1 differs significantly from the most recent
value of Ar(Si) = 27.976 970 27(23)k=1. Using the results generated herein for Ar(Si) along with other IAC measurement results
for mass, volume, and the lattice spacing, the estimate of the Avogadro
constant becomes NA = 6.022 140 40(19)
× 1023 mol–1.