je7b00786_si_001.pdf (256.44 kB)
Density, Viscosity, and CO2 Solubility in the Ionic Liquid Mixtures of [bmim][PF6] and [bmim][TFSA] at 313.15 K
journal contribution
posted on 2017-12-29, 12:51 authored by Daisuke Kodama, Kayoko Sato, Masaki Watanabe, Toshiya Sugawara, Takashi Makino, Mitsuhiro KanakuboThe
density and viscosity of 1-butyl-3-methylimidazolium hexafluorophosphate
([bmim][PF6]), 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide
([bmim][TFSA]), and their mixtures were measured at 313.15 K and at
atmospheric pressure. Furthermore, the CO2 solubilities
and the CO2-saturated densities of [bmim][PF6], [bmim][TFSA], and their mixtures were determined at 313.15 K and
pressures up to 8.5 MPa using a volume-variable high-pressure apparatus.
The ionic liquid mixtures were prepared at the mole fractions of [bmim][PF6] of 0.25, 0.50, and 0.75. The CO2 solubilities
in both the mole fraction and molarity scales increased with the composition
of [bmim][TFSA], and the pressure-mole fraction curves showed a typical
behavior for the physical absorption. The CO2-saturated
density of the ionic liquid phase decreased with increasing the composition
of [bmim][PF6] and the pressure. Excess volumetric properties
were calculated from the pressure–volume–mole fraction
relations.