posted on 2020-03-16, 12:34authored byJessica
V. Fuentes, Edgar B. Zamora, Rubia Mariath, Zuoli Li, Zhenghe Xu, Flavio Vázquez, César Flores
A series of new amphoteric
block bipolymers were prepared by the
functionalization of PEO–PPO–PEO block bipolymers with
a terminal tertiary amine and subsequently, with acrylic acid derivatives
by means of Michael reaction. In addition to the chemical process
mentioned earlier, the amphoteric block bipolymers were characterized
by 1D and 2D nuclear magnetic resonance, size exclusion chromatography,
and thermo-gravimetric analysis. Afterward, the dehydrating capacity
of the new demulsifiers was evaluated in three heavy crude oils and
one light crude oil. Finally, a quantitative structure–activity
relationship analysis was deployed using quantum parameters of the
amphoteric bipolymers and physicochemical parameters of the crude
oils. For the training set and the external validation, a set of 24
water removal efficiency (WRE) values were considered. In the scope
of the training set, six equations, V1–V6, fulfilled the restriction
of Q2 value > 0.60. Regarding the external
validation, the rm2 criterion
>0.50 was considered to be the main restriction to validate the
eqs
V1–V6. In this case, the eq V1 showed the highest rm2 value of 0.72, which was therefore singled
out as the best to calculate the WRE value for the amphoteric block
bipolymers. Conclusively, the theoretical and experimental results
demonstrated that a single amphoteric block bipolymer, with an adequate
functional group, can evidently act as the demulsifier agent for great
variety of crude oils in a more efficient manner than a conventional
combination of several commercial polyethers.