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Crystallographic Structure Determination of Both [5,6]- and [6,6]-Isomers of Lithium-Ion-Containing Diphenylmethano[60]fullerene

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posted on 2017-05-10, 00:00 authored by Hiroshi Okada, Hiroki Kawakami, Shinobu Aoyagi, Yutaka Matsuo
Organic functionalization of lithium-ion-containing [60]­fullerene, Li+@C60, was performed by using diphenyl­(diazo)­methane as a stable, readily available diazo compound to obtain lithium-ion-containing [5,6]- and [6,6]-diphenylmethano[60]­fullerenes, Li+@C61Ph2. The bis­(trifluoromethanesulfonyl)­imide (TFSI) salts of [5,6]- and [6,6]-Li+@C61Ph2 were successfully separated by using a cation exchange column with eluent containing LiTFSI. Improved separation protocol and high crystallinity of ionic components in less polar solvents enabled separate crystallization of each isomer. Both [5,6]-open and [6,6]-closed structures of Li+@C61Ph2 were determined by synchrotron radiation X-ray crystallography. Elucidating the [5,6]-open methano[60]­fullerene (fulleroid) structure will contribute to materials research on fulleroids.

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