Crystalline
Coordination Networks of Zero-Valent Metal
Centers: Formation of a 3‑Dimensional Ni(0) Framework with m‑Terphenyl Diisocyanides

Agnew, Douglas
W.; DiMucci, Ida M.; Arroyave, Alejandra; Gembicky, Milan; Moore, Curtis E.; MacMillan, Samantha N.; Rheingold, Arnold L.; Lancaster, Kyle M.; Figueroa, Joshua S.

doi:10.1021/jacs.7b09569.s001

ja7b09569_si_001.pdf (2.72 MB)

Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3‑Dimensional Ni(0) Framework with m‑Terphenyl Diisocyanides

journal contribution

posted on 2017-11-13, 00:00 authored by Douglas W. Agnew, Ida M. DiMucci, Alejandra Arroyave, Milan Gembicky, Curtis E. Moore, Samantha N. MacMillan, Arnold L. Rheingold, Kyle M. Lancaster, Joshua S. Figueroa

A permanently porous, three-dimensional metal–organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNAr^Mes2]₂, and the d¹⁰ Ni(0) precursor Ni(COD)₂, produces a porous metal–organic material featuring tetrahedral [Ni(CNAr^Mes2)₄]_n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N₂-adsorption profile.

Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3‑Dimensional Ni(0) Framework with m‑Terphenyl Diisocyanides

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