American Chemical Society
Browse
ja067102v_si_002.cif (32.79 kB)

Cross-Bridging Reaction of 5,20-Diethynyl Substituted Hexaphyrins to Vinylene-Bridged Hexaphyrins

Download (32.79 kB)
dataset
posted on 2007-01-24, 00:00 authored by Masaaki Suzuki, Atsuhiro Osuka
5,20-Diethynyl substituted [26]hexaphyrins(1.1.1.1.1.1) undergo a thermal or spontaneous cross-bridging reaction to provide trans-vinylene-bridged [26]hexaphyrins, probably through strongly folded conformations. Facile aromatic−antiaromatic switching of vinylene-bridged hexaphyrins has been demonstrated upon two-electron redox processes. Curiously, a resonance contributor of the vinylene-bridged hexaphyrins is regarded as [16]diazaannuleno[16]diazaannulene but its contribution should be minor because of the perpendicular geometry of the bridge. Vinylene-bridged hexaphyrin serves as an effective ligand that coordinates two zinc(II) ions using the central vinylene double bond in a η2-fashion along with the three pyrrolic nitrogen atoms.

History