Cp2TiCl2‑Catalyzed Photoredox
Allylation of Aldehydes with Visible Light

Gualandi, Andrea; Calogero, Francesco; Mazzarini, Martino; Guazzi, Simone; Fermi, Andrea; Bergamini, Giacomo; Cozzi, Pier Giorgio

doi:10.1021/acscatal.0c00348.s001

cs0c00348_si_001.pdf (6.02 MB)

Cp₂TiCl₂‑Catalyzed Photoredox Allylation of Aldehydes with Visible Light

journal contribution

posted on 2020-03-10, 15:24 authored by Andrea Gualandi, Francesco Calogero, Martino Mazzarini, Simone Guazzi, Andrea Fermi, Giacomo Bergamini, Pier Giorgio Cozzi

A Barbier-type Cp₂TiCl₂-mediated (10 mol %) photoredox allylation of aldehydes under irradiation with visible light (blue light-emitting diodes (LEDs), 450 nm) and in the presence of an organic dye (3DPAFIPN, 5 mol %) with allylbromides is described.