ol020167s_si_002.pdf (25.08 kB)
Coupling Reactions of α-Bromoalkenyl Phosphonates with Aryl Boronic Acids and Alkenyl Borates
journal contribution
posted on 2002-11-01, 00:00 authored by Yuichi Kobayashi, Anthony D. WilliamTransition metal-catalyzed arylation and alkenylation of the α-bromoalkenyl phosphonates were investigated with organoboranes and -borates.
Arylation was successful with the aryl boronic acids and a palladium catalyst, while alkenylation was found to proceed with alkenyl borates
and a nickel catalyst. In addition, an intramolecular Diels−Alder reaction of the diene prepared by the alkenylation afforded the corresponding
adduct.