om8b00938_si_001.pdf (2.11 MB)
Chlorine-Substituted Germabenzene: Generation and Application as a Precursor for Aryl-Substituted Germabenzenes
journal contribution
posted on 2019-01-23, 20:34 authored by Canon Kaiya, Katsunori Suzuki, Makoto YamashitaGermabenzene bearing
a reactive chlorine group on the germanium
atom was generated and characterized by nuclear magnetic resonance
spectroscopy. Reactions of the in situ generated chlorogermabenzene
with aryllithium reagents gave isolable germabenzenes bearing aryl
groups, such as mesityl or acridinyl groups, on the germanium atom.
This reaction constitutes the first example for a nucleophilic aromatic
substitution of heavy heterobenzenes at the main group center.