am6b12150_si_001.pdf (1.08 MB)
Chestnut-Like TiO2@α-Fe2O3 Core–Shell Nanostructures with Abundant Interfaces for Efficient and Ultralong Life Lithium-Ion Storage
journal contribution
posted on 2016-12-15, 00:00 authored by Jingling Yang, Qili Wu, Xianfeng Yang, Shiman He, Javid Khan, Yuying Meng, Xiuming Zhu, Shengfu Tong, Mingmei WuTransition
metal oxides caused much attention owing to the scientific
interests and potential applications in energy storage systems. In
this study, a free-standing three-dimensional (3D) chestnut-like TiO2@α-Fe2O3 core–shell nanostructure
(TFN) is rationally synthesized and utilized as a carbon-free electrode
for lithium-ion batteries (LIBs). Two new interfaces between anatase
TiO2 and α-Fe2O3 are observed
and supposed to provide synergistic effect. The TiO2 microsphere
framework significantly improves the mechanical stability, while the
α-Fe2O3 provides large capacity. The abundant
boundary structures offer the possibility for interfacial lithium
storage and electron transport. The as-prepared TFN delivers a high
capacity of 820 mAh g–1 even after 1000 continuous
cycles with a Coulombic efficiency of ca. 99% at a current of 500
mA g–1, which is better than the works reported
previously. A thin gel-like SEI (solid electrolyte interphase) film
and Fe0 phase yielded during charge/discharge cycling have
been confirmed which makes it possible to alleviate the volumetric
change and enhance the electronic conductivity. This confirmation
is helpful for understanding the mechanism of lithium-ion storage
in α-Fe2O3-based materials. The as-prepared
free-standing TFN with excellent stability and high capacity can be
an appropriate candidate for carbon-free anode material in LIBs.
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Keywords
LIBboundary structures offerUltralong Life Lithium-Ion Storage Transition metal oxidesas-prepared TFNα- Fe 2 O 3Fe 0 phasegel-like SEIanatase TiO 2carbon-free electrodeAbundant Interfaceselectrolyte interphaseTiO 2 microsphere frameworkcapacitylithium storageCoulombic efficiencycarbon-free anode materialelectron transportlithium-ion storageenergy storage systemslithium-ion batteries
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