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Catalyst-Free and Metal-Free Electrophilic Bromoamidation of Unactivated Olefins Using the N‑Bromosuccinimide/Sulfonamide Protocol

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posted on 2015-03-06, 00:00 authored by Wesley Zongrong Yu, Feng Chen, Yi An Cheng, Ying-Yeung Yeung
An efficient, catalyst-free, and metal-free bromoamidation of unactivated olefins has been developed. 4-(Trifluoromethyl)­benzenesulfonamide and N-bromosuccinimide were used as the nitrogen and halogen sources, respectively. The methodology is applicable to both cyclic and aliphatic olefins.

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