ja108051u_si_001.pdf (1.45 MB)
Carboranylamidinates
journal contribution
posted on 2010-11-10, 00:00 authored by Peter Dröse, Cristian G. Hrib, Frank T. EdelmannCarboranylamidinate anions are readily accessible via addition of N,N′-dialkylcarbodiimides to lithio-ortho-carborane. They represent a novel difunctional boron-rich ligand system for main group and transition elements (Li, Sn, Cr). Initial structural investigations revealed an unexpected N,C-coordination mode instead of N,N′-chelation.