Carbon−Hydrogen Bond Activation of Aromatic Imines by (Cp*2SmH)2
journal contributionposted on 17.09.1996 by Nora S. Radu, Stephen L. Buchwald, Brian Scott, Carol J. Burns
Any type of content formally published in an academic journal, usually following a peer-review process.
Treatment of (Cp*2SmH)2 with 2-phenyl-1-pyrroline forms product 1, via ortho-metalation. Complex 1 was characterized spectroscopically and by single-crystal X-ray diffraction. The C−H bond activation reaction also occurs for acyclic aromatic ketimines and aldimines.